GHADWAL RESEARCH GROUP
Molecular Inorganic Chemistry and Catalysis
advancing low-valent main-group chemistry for catalysis and materials
2012-2013
45. R. S. Ghadwal,* S. O. Reichmann, F. Engelhardt, D. M. Andrada, G. Frenking
Chem. Commun. 2013, 49, 9440–9442.
Facile Access to Silyl-functionalized N-Heterocyclic Olefins with HSiCl3
44. R. S. Ghadwal,* R. Azhakar, K. Pröpper, B. Dittrich, M. John
Chem. Commun. 2013, 49, 5987–5989.
Selective Functionalization of a Bis-silylene
43. R. Azhakar, R. S. Ghadwal,* H. W. Roesky,* J. Hey, L. Krause, D. Stalke*
Dalton. Trans. 2013, 42, 10277–10281.
Mixed Valence η6–Arene Cobalt(I) and Cobalt(II) Compounds
42. R. S. Ghadwal,* R. Azhakar, H. W. Roesky*
Acc. Chem. Res. 2013, 46, 444–456.
Dichlorosilylene: A High Temperature Transient Species to an Indispensable Building Block
41. R. Azhakar, R. S. Ghadwal,* H. W. Roesky,* R. A. Mata,* H. Wolf, R. Herbst-Irmer, D. Stalke*
Chem. Eur. J. 2013, 19, 3715–3720.
Reaction of N-Heterocyclic Silylenes with Thioketone: Formation of Silicon-Sulfur Three- (Si-C-S) and Five- (Si-C-C-C-S) Membered Ring Systems
40. P. P. Samuel, R. Azhakar, R. S. Ghadwal,* S. S. Sen, H. W. Roesky,* M. Granitzka, J. Matussek, R. Herbst-Irmer, D. Stalke*
Inorg. Chem., 2012, 51, 11049–11054.
Stable Silaimines with Three- and Four-Coordinate Silicon Atoms
39. R. Azhakar, H. W. Roesky,* R. S. Ghadwal,* J. J. Holstein, B. Dittrich*
Dalton Trans. 2012, 41, 9601–9603.
An Access to Base-Stabilized Three-Membered Silicon Heterocycles
38. R. S. Ghadwal,* R. Azhakar, H. W. Roesky,* K. Pröpper, B. Dittrich, C. Goedecke, G. Frenking*
Chem. Commun. 2012, 48, 8186–8188.
Donor-Acceptor Stabilized Silaformyl Chloride
37. R. Azhakar, R. S. Ghadwal,* H. W. Roesky,* M. Granitzka, D. Stalke*
Organometallics 2012, 31, 5506–5510.
Reactivity Studies of a Stable N-Heterocyclic Silylene with Triphenylsilanol and Pentafluorophenol
36. A. P. Singh, R. S. Ghadwal,* H. W. Roesky,* J. J. Holstein, B. Dittrich,* J.-P. Demers, V. Chevelkov, A. Lange
Chem. Commun. 2012, 48, 7574–7576.
Lewis Base Mediated Dismutation of Trichlorosilane
35. R. Azhakar, R. S. Ghadwal,* H. W. Roesky,* H. Wolf, D. Stalke*
Organometallics 2012, 31, 4588–4592.
Facile Access to the Functionalized N-Donor Stabilized Silylenes PhC(NtBu)2SiX (X = PPh2, NPh2, NCy2, NiPr2, NMe2, N(SiMe3)2, OtBu)
34. R. Azhakar, R. S. Ghadwal,* H. W. Roesky,* H. Wolf, D. Stalke*
Chem. Commun. 2012, 48, 4561–4563.
A Debut for Base Stabilized Monoalkylsilylenes
33. R. Azhakar, R. S. Ghadwal,* H. W. Roesky,* J. Hey, D. Stalke*
Chem. Asian J. 2012, 7, 528–533.
Facile Access to Transition-Metal-Carbonyl Complexes with an Amidinate-Stabilized Chlorosilylene Ligand
32. R. Azhakar, R. S. Ghadwal, H. W. Roesky,* J. Hey, D. Stalke*
Dalton Trans. 2012, 41, 1529–1533.
Double N-H Bond Activation of N,N'-Bis-Substituted Hydrazines with Stable N-Heterocyclic Silylene
31. R. Azhakar, R. S. Ghadwal,* H. W. Roesky,* H. Wolf, D. Stalke*
J. Am. Chem. Soc. 2012, 134, 2423–2428.
Stabilization of Low Valent Silicon Fluorides in the Coordination Sphere of Transition Metals