GHADWAL RESEARCH GROUP
Molecular Inorganic Chemistry and Catalysis
advancing low-valent main-group chemistry for catalysis and materials
2004-2011
2011
30. R. S. Ghadwal,* R. Azhakar, H. W. Roesky,* K. Pröpper, B. Dittrich,* S. Klein, G. Frenking*
J. Am. Chem. Soc. 2011, 133, 17552–17555.
Donor-Acceptor-Stabilized Silicon Analogue of an Acid Anhydride
29. P. W. Percival, J.-C. Brodovitch, M. Mozafari, A. Mitra, R. West, R. S. Ghadwal, R. Azhakar, H. W. Roesky
Chem. Eur- J. 2011, 17, 11970–11973.
Free Radical Reactivity of Mono- and Dichlorosilylene with Muonium
28. R. S. Ghadwal,* R. Azhakar, K. Pröper, J. J. Holstein, B. Dittrich,* H. W. Roesky*
Inorg. Chem. 2011, 50, 8502–8508.
N-Heterocyclic Carbene Stabilized Dichlorosilylene Transition-Metal Complexes of V(I), Co(I), and Fe(0)
27. R. Azhakar, R. S. Ghadwal, H. W. Roesky,* J. Hey, D. Stalke*
Organometallics 2011, 30, 3853–3858.
Reactions of Stable N-Heterocyclic Silylenes with Ketones and 3,5-Di-tert-butyl-o-benzoquinone
26. R. S. Ghadwal, H. W. Roesky, K. Pröpper, B. Dittrich, S. Klein, G. Frenking
Angew. Chem. Int. Ed. 2011, 50, 5374–5378; Angew. Chem. 2011, 123, 5486–5490.
A Dimer of Silaisonitrile with Two-Coordinate Silicon Atoms
(Selected as a Very Important Paper)
25. S. S. Sen, R. S. Ghadwal, K. Kratzert, D. Stern, H. W. Roesky, D. Stalke
Organometallics 2011, 30, 1030–1033.
Synthesis and Structure of [{PhC(NtBu)2}2Ge2(μ-S)2Cl2] and a Germanium Dithiocarboxylate Analogue
24. R. G. Ghadwal, K. Pröpper, B. Dittrich, P. G. Jones, H. W. Roesky
Inorg. Chem. 2011, 50, 358–364.
Neutral Pentacoordinate Silicon Fluorides Derived from Amidinate, Guanidinate, and Triazapentadienate Ligands and Base-Induced Disproportionation of Si2Cl6 to Stable Silylenes
2010
23. R. S. Ghadwal, H. W. Roesky, C. Schulzke, M. Granitzka
Organometallics 2010, 29, 6329–6333.
N-Heterocyclic Carbene Stabilized Dichlorosilaimine IPr·Cl2Si=NR
22. R. S. Ghadwal, H. W. Roesky, M. Granitzka, D. Stalke
J. Am. Chem. Soc. 2010, 132, 10018–10020.
A Facile Route to Functionalized N-Heterocyclic Carbene (NHC) with NHC Base Stabilized Dichlorosilylene
21. R. S. Ghadwal, S. S. Sen, H. W. Roesky, S. Merkel, M. Granitzka, D. Stalke
Angew. Chem. Int. Ed. 2010, 49, 3952–3955; Angew. Chem. 2010, 122, 4044–4047.
Convenient Access to Monosilicon Epoxides with Penta-Coordinate Silicon
20. R. S. Ghadwal, H. W. Roesky, S. Merkel, D. Stalke
Chem.- Eur. J. 2010, 16, 85–88.
Ambiphilicity of Dichlorosilylene in a Single Molecule
19. J. Li, S. Merkel, J. Henn, K. Meindl, A. Döring, H. W. Roesky, R. S. Ghadwal, D. Stalke
Inorg. Chem. 2010, 49, 775–777.
Lewis-Base-Stabilized Dichlorosilylene: A Two-Electron σ-Donor Ligand
2009
18. R. S. Ghadwal, S. S. Sen, H. W. Roesky, G. Tavcar, S. Merkel, D. Stalke
Organometallics 2009, 28, 6347–6377.
Neutral Penta- and Hexacoordinate N-Heterocyclic Carbene Complexes Derived from SiX4 (X=F, Br)
17. R. S. Ghadwal, H. W. Roesky, S. Merkel, J. Henn, D. Stalke
Angew. Chem. Int. Ed. 2009, 48, 5683–5686.; Angew. Chem. 2009, 121, 5793–5796.
Lewis Base Stabilized Dichlorosilylene
16. R. S. Ghadwal, H. W. Roesky, R. Herbst-Irmer, P. G. Jones
Z. Anorg. Allg. Chem. 2009, 635(3), 431–433.
N-Heterocyclic Carbene Adducts of Aluminum Triiodide
15. N. B. Sharma, R. S. Ghadwal, A. Singh
Main Group Met. Chem. 2009, 32 (5), 253–262.
Synthesis and Spectroscopic Structural Elucidation of Some Novel Heterobimetallic Complexes of Monoorganotin(IV)
2004-2008 (PhD)
14. R. S. Ghadwal, N. B. Sharma, A. Singh
Main Group Met. Chem. 2008, 31(5), 217–225.
Synthesis and Characterisation of Some Novel Seven-Membered Heterocyclic Antimony(III) Glycolate Complexes
13. R. S. Ghadwal, A. Singh
Indian J. Chem. Sec. A 2007, 46A, 768–771.
Synthesis, Reaction and Spectroscopic Properties of the New Examples of Metallatranes
12. R. S. Ghadwal, A. Singh
Indian J. Chem., Sec. A 2006, 45A, 2644–2649.
Synthesis and Spectroscopic Characterization of Mixed Ligand Complexes of Oxovanadium(V)
11. R. S. Ghadwal, A. Singh
J. Chem. Res. 2006, 451–455.
Synthesis and Spectroscopic Characterization of a New Class of Heterobimetallic Homoleptic Diethanolaminate Complexes of Niobium(V) and Tantalum(V)
10. R. S. Ghadwal, R. C. Mehrotra, A. Singh
Main Group. Met. Chem. 2006, 29, 1–9.
Synthesis and Spectroscopic [IR, NMR (1H, 27Al, and 51V)] Characterization of Heterobimetallic Glycolate- and Diethanolaminate-Isopropoxide Complexes of Aluminium
09. R. S. Ghadwal, A. Singh
J. Chem. Sci. 2006, 118(2), 165–170.
Synthesis and Spectroscopic Properties of Homo- and Heterobimetallic Complexes of Oxovanadium(V)
08. R. S. Ghadwal, A. Singh, R. C. Mehrotra
Phosphorus, Sulfur and Silicon 2006, 181,113–123.
Synthesis and Spectroscopic Properties of First Series of Heteronuclear Derivatives Containing Organosilicon/ Organotin(IV) and Oxovanadium(V) Moieties
07. R. S. Ghadwal, N. B. Sharma, A. Singh
Main Group Met. Chem. 2005, 28, 173–183.
Preparation and Characterization of Heteronuclear Mixed Ligand Complexes of Aluminium Containing Organosilicon/ Organotin Moieties
06. R. S. Ghadwal, A. Singh
Indian J. Chem. Sec. A 2005, 44A, 2439–2444.
Synthesis and Characterization of Heterobimetallic N-Substituted Diethanolaminate-Alkoxides of Niobium(V)
05. R. S. Ghadwal, R. C. Mehrotra, A. Singh
Transition Met. Chem. 2005, 30, 836–844.
Synthesis and Spectroscopic Characterization of Two Different Types of Heterobimetallic Glycolate Complexes of Niobium(V)
04. R. S. Ghadwal, R. C. Mehrotra, A. Singh
J. Chem. Res. 2005, 352–355.
Preparation and Spectroscopic Characterization of a Series of Heterobimetallic N-Phenyldiethanolaminate-Alkoxide Derivatives of Oxovanadium(V)
03. R. S. Ghadwal, A. Singh, R. C. Mehrotra
Transition Met. Chem. 2005, 30, 268–272.
Synthesis and Characterization Heterobimetallic N-(Hydroxyethyl)salicylaldiminate-isopropoxide Complexes of Oxovanadium(V)
02. R. S. Ghadwal, R. C. Mehrotra, A. Singh
Main Group Met. Chem. 2004, 27, 199–209.
Preparation and Spectroscopic [IR, NMR (1H, 11B, 27Al, 51V)] Characterization of New Types of Heteronuclear Derivatives of Aluminium and Boron Containing Bis(2,5-dimethyl-2,5-hexanediolato)oxovanadium(V) Group
01. R. S. Ghadwal, M. Sharma, A. Singh, R. C. Mehrotra
Transition Met. Chem. 2004, 29, 419–424.
Synthesis and Spectroscopic Characterization of Six-Coordinate Complexes of Oxovanadium(V)